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乐斯苯危险特性 | 2011-11-15 11:29:00
乐斯苯危险特性
乐斯苯别名:毒死蜱,氯蜱硫磷,杀死虫,蓝珠,化学名0,0一二乙基0一(3,5,6FG RNV一2一吡啶基)硫代删黾。分子式:C9HI,CL:,N0:;PS。分子量:350.3。
乐斯苯为农用杀虫剂。原药为白色颗粒状结晶,有硫醇臭味。相对密度1.398(43.5℃),熔点:41.5-43.5℃,难溶于水,溶于大多数有机溶剂。
乐斯苯40.7%乳油为草黄色液体,有硫醇臭味,相对密度1.18,闪点35℃。杀死虫蓝珠14%颗粒剂为蓝色颗粒,相对密度大于1,熔点90℃,不溶于水。
危险特性:中等毒杀虫剂,原药可燃,乳油易燃,原药大鼠经口LD硼:163mg/kg;大鼠经皮L‰:>2000mg/kg;对动物试验眼睛有轻度刺激,对皮肤有明显刺激,甚至引起灼伤。大鼠亚急性经口无作用剂量为0.03mg/kg,慢性经口在试剂剂鼠经口LD,~o:163mg/kg;量下未见致畸、致突变、致癌作用。对鱼类及水生物mg/kg毒性较高。对蜜蜂有毒。乐斯本40.7%乳油大鼠经口L蹁:590mg/kg;兔经皮LD硼:2330mg/kg。对皮肤、眼睛有刺激作用。杀死虫蓝珠14%颗粒剂大鼠经口LD硼:>2000mg/kg:大鼠经皮LD训:>2000mg/kg:大鼠吸入LC.~o:>0.007mg/L(7小时)对眼睛、皮肤有刺激性。
乐斯苯事故应急措施:1)消防方法:用干粉、泡沫和砂土灭火。消防人员须戴防毒面具,穿防护服。2)急救:皮肤污染用肥皂及清水冲洗。误服迅速催吐、洗胃,并送医院急救。常用的解毒药有阿托品。
储运须知包装标志:毒害品。乳油增加副标志:易燃液体。包装方法:(II)类,(III)类。铁桶或玻璃瓶外钙塑箱(纸箱或木箱)内衬瓦楞纸,粉剂用编织袋内衬塑料袋。储运条件:现场不得吸烟、喝水、进食。不能与粮食、食物、种子、饲料、各种日用品混装混运。操作人员必须穿工作服,戴橡胶防护手套。轻装轻卸,防止容器破损。防潮、防高温曝晒、防雨淋。寒冷季节要注意保持库温在结晶点以上,防止冻裂容器及变质。严禁接触火种。储存于阴凉、干燥、通风的仓间内。专人保管。
泄漏处理:乳剂用砂土吸收倒至空旷地方深埋。污染地面撒上石灰,再用大量水冲洗,经稀释的污水放入废水系统。粉剂扫起装入袋中备用。
乐斯苯别名:毒死蜱,氯蜱硫磷,杀死虫,蓝珠,化学名0,0一二乙基0一(3,5,6FG RNV一2一吡啶基)硫代删黾。分子式:C9HI,CL:,N0:;PS。分子量:350.3。
乐斯苯为农用杀虫剂。原药为白色颗粒状结晶,有硫醇臭味。相对密度1.398(43.5℃),熔点:41.5-43.5℃,难溶于水,溶于大多数有机溶剂。
乐斯苯40.7%乳油为草黄色液体,有硫醇臭味,相对密度1.18,闪点35℃。杀死虫蓝珠14%颗粒剂为蓝色颗粒,相对密度大于1,熔点90℃,不溶于水。
危险特性:中等毒杀虫剂,原药可燃,乳油易燃,原药大鼠经口LD硼:163mg/kg;大鼠经皮L‰:>2000mg/kg;对动物试验眼睛有轻度刺激,对皮肤有明显刺激,甚至引起灼伤。大鼠亚急性经口无作用剂量为0.03mg/kg,慢性经口在试剂剂鼠经口LD,~o:163mg/kg;量下未见致畸、致突变、致癌作用。对鱼类及水生物mg/kg毒性较高。对蜜蜂有毒。乐斯本40.7%乳油大鼠经口L蹁:590mg/kg;兔经皮LD硼:2330mg/kg。对皮肤、眼睛有刺激作用。杀死虫蓝珠14%颗粒剂大鼠经口LD硼:>2000mg/kg:大鼠经皮LD训:>2000mg/kg:大鼠吸入LC.~o:>0.007mg/L(7小时)对眼睛、皮肤有刺激性。
乐斯苯事故应急措施:1)消防方法:用干粉、泡沫和砂土灭火。消防人员须戴防毒面具,穿防护服。2)急救:皮肤污染用肥皂及清水冲洗。误服迅速催吐、洗胃,并送医院急救。常用的解毒药有阿托品。
储运须知包装标志:毒害品。乳油增加副标志:易燃液体。包装方法:(II)类,(III)类。铁桶或玻璃瓶外钙塑箱(纸箱或木箱)内衬瓦楞纸,粉剂用编织袋内衬塑料袋。储运条件:现场不得吸烟、喝水、进食。不能与粮食、食物、种子、饲料、各种日用品混装混运。操作人员必须穿工作服,戴橡胶防护手套。轻装轻卸,防止容器破损。防潮、防高温曝晒、防雨淋。寒冷季节要注意保持库温在结晶点以上,防止冻裂容器及变质。严禁接触火种。储存于阴凉、干燥、通风的仓间内。专人保管。
泄漏处理:乳剂用砂土吸收倒至空旷地方深埋。污染地面撒上石灰,再用大量水冲洗,经稀释的污水放入废水系统。粉剂扫起装入袋中备用。
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