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光气的健康危害与中毒预防 | 2012-2-24 8:55:00

光气,又称碳酰氯,无色气体,有腐草臭味。是由一氧化碳和氯的混合物通过活性炭催化剂制得,主要用于有机合成,如制中间体、农药、染料等。光气的密度为1.392,熔点-118,沸点8.3,微溶于水,并可逐渐水解,较易溶于苯、甲苯等。
  光气的毒性比氯气大10倍,曾用作化学毒剂。光气的储存应该避免接触水、水蒸气,远离潮湿地方,要储存在密闭的钢容器内,远离工作区和其他物品,远离热气管和冷却管道。

  按照国家的有关规定,光气是严格限制使用的化学气体。因此,一般情况下只有从事与光气有关的相关工作的人员才有机会接触。而发生光气事故的,大多是在光气生产和使用过程中由于设备密闭不严、使用不当、储运容器锈蚀破裂等造成泄漏,引发中毒。

  光气经呼吸道吸入后,会引起以急性呼吸系统损害为主的全身性疾病。表现为刺激反应、轻度、中度、重度中毒。与氯气中毒的表现极为相似,但更严重。值得注意的是,光气中毒发病前有一定的潜伏期。人吸入光气后,一般有2-24小时的潜伏期。吸入量越多,则潜伏期越短,病情越严重。人吸入浓度较低的光气时,局部刺激症状可不明显,但经过一段潜伏期后,则可直接损害毛细血管内膜,出现肺水肿。当吸入较高浓度光气时,中毒者可发生支气管痉挛,有中毒者可在肺水肿出现之前即出现窒息症状。

  一旦发现光气中毒,应该立即将病人移至通风处吸入新鲜空气,并保持安静和暖和。用镇静剂、镇咳剂、支气管镇痉剂、吸氧等进行治疗,还可用碱性液,如5%碳酸氢钠溶液5毫升雾化吸入。同时,立即送医院进行针对性治疗。

  预防光气中毒,从生产现场来说,要实现自动化、密闭化,让工人在远离生产设备的室内操作;生产设备可设置成露天或半露天,保证自然良好的通风;生产车间要安装毒气破坏系统,一旦有光气泄漏可立即被吸入破坏系统予以破坏;要采用新工艺,光气不再作半成品进行储运而直接进入下道工序合成为成品。从个人来说,一旦发生意外,要努力不让毒气吸入人体,并尽快撤离污染现场;作业人员应配备防毒面具和空气呼吸器。

 

Re:光气的健康危害与中毒预防 | 2012-2-24 8:56:44
章仁根光气要接触使用,健康危害与中毒预防要知晓。
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原创 | 2016-9-6 17:52:49
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原创 | 2016-9-28 17:26:53
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原创 | 2016-9-30 12:02:59
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Re:在漫画中识别身边的违章 | 2016-10-12 12:21:34
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Re:在漫画中识别身边的违章 | 2016-10-14 17:47:15
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Re:在漫画中识别身边的违章 | 2016-10-15 20:01:46
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Re:在漫画中识别身边的违章 | 2016-10-20 22:27:34
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Re:在漫画中识别身边的违章 | 2016-10-21 13:17:03
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Re:在漫画中识别身边的违章 | 2016-10-21 15:39:02
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Re:在漫画中识别身边的违章 | 2016-10-21 19:18:17
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Re:在漫画中识别身边的违章 | 2016-10-22 4:27:57
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Re:在漫画中识别身边的违章 | 2016-10-22 16:00:59
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Re:在漫画中识别身边的违章 | 2016-10-22 22:43:22
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Re:在漫画中识别身边的违章 | 2016-10-23 14:31:22
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Re:在漫画中识别身边的违章 | 2016-10-23 14:40:33
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Re:在漫画中识别身边的违章 | 2016-10-23 15:16:41
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Re:在漫画中识别身边的违章 | 2017-2-19 13:44:38
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By:kixbf(游客) | 个人主页 | 引用 | 返回 | 删除 | 回复
Re:在漫画中识别身边的违章 | 2017-3-2 20:58:57
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