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化学品氯化过程危险性分析 | 2010-12-13 8:55:00
 氯化  
  
  以氯原子取代有机化合物中氢原子的过程称为氯化。如由甲烷制甲烷氯化物、苯氯化制氯苯等。常用的氯化剂有:液态或气态氯、气态氯化氢和各种浓度的盐酸、磷酸氯(三氯氧化磷)、三氯化磷(用来制造有机酸的酰氯)、硫酰氯(二氯硫酰)、次氯酸酯等。  
 
  氯化过程危险性分析与防火要点: 
 
  (1)氯化反应的火灾危险性主要决定于被氯化物质的性质及反应过程的条件。反应过程中所用的原料大多是有机易燃物和强氧化剂,如甲烷、乙烷、苯、酒精、天然气、甲苯、液氯等。如生产1t甲烷氯化物需要2006m3甲烷、6960kg液氯,生产过程中同样具有着火爆炸危险。所以,应严格控制各种着火源,电气设备应符合防火防爆要求。 
 
  (2)氯化反应中最常用的氯化剂是液态或气态的氯。氯气本身毒性较大,氧化性极强,储存压力较高,一旦泄漏是很危险的。所以贮罐中的液氯在进入氯化器使用之前,必须先进人蒸发器使其气化。在一般情况下不准把储存氯气的气瓶或槽车当贮罐使用,因为这样有可能使被氯化的有机物质倒流进气瓶或槽车引起爆炸。对于一般氯化器应装设氯气缓冲罐,防止氯气断流或压力减小时形成倒流。
  (3)氯化反应是一个放热过程,尤其在较高温度下进行氯化,反应更为剧烈。例如在环氧氯丙烷生产中,丙烯需预热至3000左右进行氯化,反应温度可升至500,在这样高的温度下,如果物料泄漏就会造成着火或引起爆炸。因此,一般氯化反应设备必须有良好的冷却系统,并严格控制氯气的流量,以免因流量过快,温度剧升而引起事故。 
 
  (4)由于氯化反应几乎都有氯化氢气体生成,因此所用的设备必须防腐蚀,设备应保证严密不漏。因为氯化氢气体易溶于水中,通过增设吸收和冷却装置就可以除去尾气中绝大部分氯化氢。 
 
 

Re:化学品氯化过程危险性分析 | 2010-12-13 8:59:18
章仁根氯化过程有危险,防范措施要落实.
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原创 | 2016-9-6 17:56:04
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原创 | 2016-9-28 17:29:54
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原创 | 2016-9-30 12:06:16
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Re:在漫画中识别身边的违章 | 2016-10-7 23:44:21
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Re:在漫画中识别身边的违章 | 2016-10-8 14:40:02
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Re:在漫画中识别身边的违章 | 2016-10-11 13:23:10
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Re:在漫画中识别身边的违章 | 2016-10-15 15:39:37
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Re:在漫画中识别身边的违章 | 2016-10-19 12:45:03
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Re:在漫画中识别身边的违章 | 2016-10-19 14:10:41
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Re:在漫画中识别身边的违章 | 2016-10-20 17:21:15
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Re:在漫画中识别身边的违章 | 2016-10-20 23:35:40
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Re:在漫画中识别身边的违章 | 2016-10-21 2:38:48
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Re:在漫画中识别身边的违章 | 2016-10-21 15:26:54
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Re:在漫画中识别身边的违章 | 2016-10-22 21:17:43
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Re:在漫画中识别身边的违章 | 2016-10-23 15:03:56
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Re:在漫画中识别身边的违章 | 2017-2-20 0:18:44
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Re:在漫画中识别身边的违章 | 2017-2-20 17:01:24
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Re:在漫画中识别身边的违章 | 2017-3-4 13:17:10
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Re:在漫画中识别身边的违章 | 2017-3-4 13:50:25
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